Skip to main content
SpringerLink
Log in

Occurrence of solid-phase topochemical polymerization in single crystals of a monomer simultaneously containing C≡C and C=C bonds

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A polymer is formed (2% yield) under the effect of heat, UV light, or γ irradiation of the crystals despite the prohibition of the occurrence of topochemical solid-phase polymerization in single crystals of 3,5-octadiyne-1,8-diol bismethacrylate. The molecular weight of the polymer is 3·103–104. This reaction takes place at C≡C-C≡C bonds. C=C bonds are not affected.

  2. 2.

    According to the data from resonant Raman spectroscopy, the structure of the main chain of the polymer formed is intermediate between polyenyne and polybutatriyne (for samples exposed to heat or UV radiation). Chains of enyne structure are also present in the samples prepared by60Co γ irradiation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. V. M. Misin and M. I. Cherkashin, Usp. Khim.,54, No. 6, 956 (1985).

    Google Scholar 

  2. V. E. Shklover, N. G. Bokii, and Yu. T. Struchkov, Usp. Khim.,46, No. 8, 1369 (1977).

    Google Scholar 

  3. O. Yu. Os'kina, V. M. Misin, and M. I. Cherkashin, Proceedings of the 13th All-Union Conference on Organic Semiconductors [in Russian], Agveran (1984), p. 21.

  4. Y. Tokura, T. T. Koda, A. Itsubo, et al., J. Chem. Phys.,85, 99 (1986).

    Google Scholar 

  5. J. Bloor, F. H. Preston, D. J. Ando, and D. N. Watchelder, Structural Studies of Macromolecules by Spectroscopic Methods [Russian translation], Khimiya, Moscow (1980), p. 85.

    Google Scholar 

  6. H. Kuzmany and P. Knoll, J. Raman Spectrosc.,17, 89 (1986).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    V. V. Berdyugin, A. I. Kuzaev, V. M. Misin, O. Yu. Os'kina, M. I. Cherkashin & P. P. Shorygin

Authors
  1. V. V. Berdyugin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. I. Kuzaev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. M. Misin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. O. Yu. Os'kina
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. I. Cherkashin
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. P. P. Shorygin
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 809–813, April, 1989.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Berdyugin, V.V., Kuzaev, A.I., Misin, V.M. et al. Occurrence of solid-phase topochemical polymerization in single crystals of a monomer simultaneously containing C≡C and C=C bonds. Russ Chem Bull 38, 727–731 (1989). https://doi.org/10.1007/BF00953280

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00953280

Keywords

Search

Navigation