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Nitrosoalkylureas with a quaternary nitrogen. 7. Quantitative relation between decomposition rate and structure of nitrosoalkylureas derived from alkylammonium salts

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The decomposition rate of the dialkyl-substituted methyl- and cyclohexylnitrosoureas correlates well with the charge on N that does not carry the nitroso group, as calculated by CNDO/2. Here the cyclohexyl residue has a greater destabilizing effect than does the methyl radical.

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Authors and Affiliations

  1. Institute of Chemistry, Ural Branch, Academy of Sciences of the USSR, Sverdlovsk

    A. A. Belyaev & L. B. Radina

Authors
  1. A. A. Belyaev
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  2. L. B. Radina
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 798–800, April, 1989.

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Belyaev, A.A., Radina, L.B. Nitrosoalkylureas with a quaternary nitrogen. 7. Quantitative relation between decomposition rate and structure of nitrosoalkylureas derived from alkylammonium salts. Russ Chem Bull 38, 717–719 (1989). https://doi.org/10.1007/BF00953277

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  • DOI: https://doi.org/10.1007/BF00953277

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