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Mechanism of thermal decomposition of N,N-dinitromethylamine

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The methylnitroamine radical does not tend to undergo intramolecular oxidation: Me.NNO2→ MeO+N2O and breaks down by decomposition into MeN: and NO2. In the presence of NO2 MeNNO2 and MeN: are efficiently oxidized to MeNO.

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Literature cited

  1. B. L. Korsunskii, G. V. Sitonina, B. S. Fedorov, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 4, 790 (1989).

    Google Scholar 

  2. R. G. Gafurov, B. S. Fedorov, and L. T. Eremenko, Izv. Akad. Nauk SSSR, Ser. Khim., 734 (1978).

  3. J. Denkstein and V. KaderÄbec, Coll. Czech. Chem. Commun.,25, 2334 (1960).

    Google Scholar 

  4. M. I. Christie, C. Gillbert, and M. A. Voisey, J. Chem. Soc., 3147 (1964).

  5. D. M. Golden, Int. J. Chem. Kinet., No. 1, 239 (1975).

    Google Scholar 

  6. V. N. Kondrat'ev, Rate Constants of Gaseous Reactions. A Handbook [in Russian], Nauka, Moscow (1970), pp. 197, 127.

    Google Scholar 

  7. K. GlÄnser and J. Troe, Ber. Bunsenges. Phys. Chem.,78, No. 2, 182 (1974).

    Google Scholar 

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Authors and Affiliations

  1. N. N. Semenov Branch, Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka

    V. V. Charskii, A. N. Pavlov, G. M. Nazin, B. L. Korsunskii & B. S. Fedorov

Authors
  1. V. V. Charskii
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  2. A. N. Pavlov
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  3. G. M. Nazin
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  4. B. L. Korsunskii
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  5. B. S. Fedorov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 794–797, April, 1989.

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Charskii, V.V., Pavlov, A.N., Nazin, G.M. et al. Mechanism of thermal decomposition of N,N-dinitromethylamine. Russ Chem Bull 38, 713–716 (1989). https://doi.org/10.1007/BF00953276

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  • DOI: https://doi.org/10.1007/BF00953276

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