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Catalytic activity of nickel complexes in vinyl hydrogen substitution reactions and styrene dimerization

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The complexes ArNiXL2 and HNiXL2 (X is halide, L is tertiary phosphine) in the presence of zinc catalyze the condensation of bromobenzene with styrene (stilbene formation).

  2. 2.

    The yield of stilbene and 1,3-diphenylbutene, the dimerization product of styrene, in the presence of pyridine is lowered according to the substitution of phenyl groups on the phosphorus ligand L by alkyl (ethyl, cyclohexyl) groups.

  3. 3.

    Change of triphenylphosphine to phenylethylphosphines and tricyclohexylphosphine in the hydride complex HNi(X)(PR3)2, the catalytic activity of which falls in the order X=Cl−≫Br−>I−, favors the dimerization of styrene in the absence of pyridine.

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Authors and Affiliations

  1. L. Ya. Karpov Scientific-Research Physicochemical Institute, Moscow

    T. E. Kron, V. S. Lopatina, L. N. Morozova, S. A. Lebedev, L. S. Isaeva, D. N. Kravtsov & é. S. Petrov

  2. A. N. Nesmeyanov Institute of Organoelemental Compounds, Academy of Sciences of the USSR, Moscow

    T. E. Kron, V. S. Lopatina, L. N. Morozova, S. A. Lebedev, L. S. Isaeva, D. N. Kravtsov & é. S. Petrov

Authors
  1. T. E. Kron
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  2. V. S. Lopatina
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  3. L. N. Morozova
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  4. S. A. Lebedev
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  5. L. S. Isaeva
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  6. D. N. Kravtsov
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  7. é. S. Petrov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 782–786, April, 1989.

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Kron, T.E., Lopatina, V.S., Morozova, L.N. et al. Catalytic activity of nickel complexes in vinyl hydrogen substitution reactions and styrene dimerization. Russ Chem Bull 38, 703–707 (1989). https://doi.org/10.1007/BF00953273

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  • DOI: https://doi.org/10.1007/BF00953273

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