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Study of the catalytic activity of metal complexes fixed on solid supports. 7. Synthesis of Pd-Sn complexes attached to macroporous anion exchangers and study of their activity in the hydrogenation of 1-hexene

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    New catalysts, Pd-Sn compounds, were synthesized and fixed to macroporous anion exchangers. They are active in hydrogenation and isomerization reactions of 1-hexene.

  2. 2.

    The catalytic properties of the Pd-Sn systems depends on the structure of the fixed compound (cluster, complex), the nature and state of the exchanger functional groups (Cl-or OH-form), and the reaction conditions (pH, PH2).

  3. 3.

    The cluster [Pd4(SnCl2)2(SnCl3)8]5− on the highly basic anion exchanger AV-17-2P (Cl-form) catalyzes mainly the hydrogenation reaction, while the complex [Pd(SnCl3)4]2− catalyzes the isomerization reaction.

  4. 4.

    The complex [Pd(SnCl3 4)]2−, fixed to the weakly basic anion exchanger AN-221 (OH-form), is active in the isomerization and hydrogenation of 1-hexene under mild conditions.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. Z. Sharf, L. D. Panfilova, N. V. Borunova, N. V. Antseva, L. P. Karapetyan, P. G. Antonov & K. M. Saldadze

  2. G. S. Petrov Scientific-Research Institute on Plastics, Moscow

    V. Z. Sharf, L. D. Panfilova, N. V. Borunova, N. V. Antseva, L. P. Karapetyan, P. G. Antonov & K. M. Saldadze

  3. Lensovet Leningrad Technological Institute, USSR

    V. Z. Sharf, L. D. Panfilova, N. V. Borunova, N. V. Antseva, L. P. Karapetyan, P. G. Antonov & K. M. Saldadze

Authors
  1. V. Z. Sharf
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  2. L. D. Panfilova
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  3. N. V. Borunova
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  4. N. V. Antseva
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  5. L. P. Karapetyan
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  6. P. G. Antonov
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  7. K. M. Saldadze
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 773–776, April, 1989.

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Sharf, V.Z., Panfilova, L.D., Borunova, N.V. et al. Study of the catalytic activity of metal complexes fixed on solid supports. 7. Synthesis of Pd-Sn complexes attached to macroporous anion exchangers and study of their activity in the hydrogenation of 1-hexene. Russ Chem Bull 38, 695–698 (1989). https://doi.org/10.1007/BF00953271

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  • DOI: https://doi.org/10.1007/BF00953271

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