Skip to main content
SpringerLink
Log in

Adsorption of the heteropolyacid H4SiW12O40 by porous substrates

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Silicotungstic heteropolyacid is sorbed by silica gels, activated charcoal, and γ-Al2O3 from water and from organic oxygen-containing solvents, forming three formations distinguishable by electron microscopy.

  2. 2.

    The relative proportions of the surface forms are determined by the type of substrate, solvent, and the HPA concentrations on the substrate. The most uniform covering is achieved when HPA is adsorbed from ethyl acetate.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. Y. Izumi, R. Hasebe, and K. Urabe, J. Catal.,84, 402 (1983).

    Google Scholar 

  2. I. V. Kozhevnikov and K. I. Matveev, Usp. Khim.,51, No. 11, 1875 (1982).

    Google Scholar 

  3. Y. Izumi and K. Urabe, Chem. Lett., 663 (1981).

  4. Modified Quartzes in Sorption, Catalysis, and Chromatography [in Russian], G. V. Lisichkin (ed.), Khimiya, Moscow (1986), p. 21.

    Google Scholar 

  5. M. Misono, N. Mizuno, T. Katamura, et al., Bull. Chem. Soc. Jpn.,55, 400 (1982).

    Google Scholar 

  6. S. Fukushima and S. Kumagai, J. Colloid Interface Sci.,42, 539 (1973).

    Google Scholar 

  7. S. Kumagai and S. Fukushima, J. Colloid Interface Sci.,56, 227 (1976).

    Google Scholar 

  8. S. M. Kulikov and I. V. Kozhevnikov, Izv. Akad. Nauk SSSR, Ser. Khim., No. 3, 498 (1981).

    Google Scholar 

  9. V. I. Spitsyn, E. A. Torchenkova, and L. P. Kazanskii, Itogi Nauki Tekh., Neorg. Khim.,10, 65 (1984).

    Google Scholar 

  10. J. F. W. Keana, M. O. Ogan, Yixin Lue, et al., J. Am. Chem. Soc.,107, No. 23, 6714 (1985).

    Google Scholar 

  11. G. M. Brown, M. R. Noe-Spirlet, W. R. Busing, and H. A. Lewy, Acta Crystallogr.,33, 1038 (1977).

    Google Scholar 

  12. Yu. I. Ermakov [Yermakov], V. F. Surovikin, G. V. Plaksin, et al., React. Kinet. Catal. Lett.,33, No. 2, 435 (1987).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk

    S. M. Kulikov, M. N. Timofeeva, I. V. Kozhevnikov, V. I. Zaikovskii, L. M. Plyasova & I. A. Ovsyanikova

Authors
  1. S. M. Kulikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. N. Timofeeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. V. Kozhevnikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. I. Zaikovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. L. M. Plyasova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. I. A. Ovsyanikova
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 763–768, April, 1989.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kulikov, S.M., Timofeeva, M.N., Kozhevnikov, I.V. et al. Adsorption of the heteropolyacid H4SiW12O40 by porous substrates. Russ Chem Bull 38, 687–691 (1989). https://doi.org/10.1007/BF00953269

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00953269

Keywords

Search

Navigation