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Reaction of 2,4,6-tri-tert-butylphenoxyl with oxygen in the presence of metal compounds

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

A dependence was found for the isomer composition of the quinolide peroxides formed upon the oxidation of 2,4,6-tri-tert-butylphenol on the coordination capacity of the metal compounds used for the oxidation and the medium. Kinetic measurements showed that the reaction of 2,4,6-tri-tert-butylphenoxyl with oxygen is accelerated in the presence of manganese diacetate.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    V. B. Vol'eva, E. V. Ivanov, I. A. Batanov & V. V. Ershov

Authors
  1. V. B. Vol'eva
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  2. E. V. Ivanov
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  3. I. A. Batanov
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  4. V. V. Ershov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 706–709, March, 1986.

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Vol'eva, V.B., Ivanov, E.V., Batanov, I.A. et al. Reaction of 2,4,6-tri-tert-butylphenoxyl with oxygen in the presence of metal compounds. Russ Chem Bull 35, 648–650 (1986). https://doi.org/10.1007/BF00953251

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  • DOI: https://doi.org/10.1007/BF00953251

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