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Synthesis and equilibrium of stereoisomers of 5-phenyl-5-thio(seleno)-2-phenyl(ethoxy)-1,3, 5-dioxaphosphorinanes

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Individual stereoisomers of 2,5-diphenyl-5-thio-1,3,5-dioxaphosphorinane, 5-phenyl-5-thio-2-ethoxy-1,3,5-dioxaphosphorinane, and 5-phenyl-5-seleno-2-ethoxy-1,3,5-dioxaphosphorinane, having the chair conformation with the axial orientation of the phenyl group on the phosphorus atom and the equatorial and axial orientation of the substituent in the 2-position, have been isolated.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR, Moscow

    B. A. Arbuzov, O. A. Erastov, A. S. Ionkin & S. N. Ignat'eva

Authors
  1. B. A. Arbuzov
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  2. O. A. Erastov
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  3. A. S. Ionkin
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  4. S. N. Ignat'eva
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 640–643, March, 1986.

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Arbuzov, B.A., Erastov, O.A., Ionkin, A.S. et al. Synthesis and equilibrium of stereoisomers of 5-phenyl-5-thio(seleno)-2-phenyl(ethoxy)-1,3, 5-dioxaphosphorinanes. Russ Chem Bull 35, 585–588 (1986). https://doi.org/10.1007/BF00953231

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  • DOI: https://doi.org/10.1007/BF00953231

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