Conclusions
In the reaction of adamantylideneadamantane with S2Cl2 at an equimolar ratio of the reagents, 2,2′-epithio-2-(2′-adamantyl)adamantane and 4-chloro-2,2′-epithio-2-(2′-adamantyl)-adamantane are formed, while with an excess of S2Cl2, the products are 4e-chloro- and 4e,4′e-dichloroadamantylideneadamantane.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 617–620, March.
Article 23, see [1].
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Tolstikov, G.A., Lerman, B.M. & Belogaeva, T.A. Study of reaction of sulfur halides with unsaturated. Compounds. 24. Reaction of sulfur monochloride with adamantylidene-adamantane. Russ Chem Bull 35, 563–566 (1986). https://doi.org/10.1007/BF00953226
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DOI: https://doi.org/10.1007/BF00953226