Conclusions
In the reaction of N-chloro-N-methoxy-N′,N′-dimethylurea with amines, a nucleophilic substitution of the chlorine atom at the N atom takes place to form N-alkoxyhydrazines, which are stable in the reaction with Me3N, pyridine, toluenesulfonamides, and give products of further transformations with Me2NH and MeONHMe.
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For Communication 28 see [1].
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 606–610, March, 1986.
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Rudchenko, V.F., Shevchenko, V.I. & Kostyanovskii, R.G. Geminal systems. Communication 29. Reactions of N-chloro-N-methoxy-N′,N′-dimethylurea with N-nucleophiles. Russ Chem Bull 35, 551–554 (1986). https://doi.org/10.1007/BF00953223
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DOI: https://doi.org/10.1007/BF00953223