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Reactions of CHCl3 and CCl4 with 1-heptene, initiated by iron, molybdenum, and manganese carbonyls and the Mo(N2)2(dppe)2 complex

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Mo(CO)6 and Mo(N2)2·(dppe)2 (dppe=Ph2PCH2CH2PPh2) initiate the addition of CHCl3 and CCl4 to α-olefins in either i-PrOH or MeCN as the medium, and here CHCl3 reacts with cleavage of the C-Cl bond.

  2. 2.

    Mn2(CO)10 does not initiate the reduction of CHCl3 by i-PrOH in the presence of 1-heptene.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    N. P. Zhiryukhina, M. A. Galkina & E. Ts. Chukovskaya

Authors
  1. N. P. Zhiryukhina
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  2. M. A. Galkina
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  3. E. Ts. Chukovskaya
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Additional information

dppe=Ph2PCH2CH2PPh2.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1426–1428, June, 1983.

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Zhiryukhina, N.P., Galkina, M.A. & Chukovskaya, E.T. Reactions of CHCl3 and CCl4 with 1-heptene, initiated by iron, molybdenum, and manganese carbonyls and the Mo(N2)2(dppe)2 complex. Russ Chem Bull 32, 1294–1296 (1983). https://doi.org/10.1007/BF00953179

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  • DOI: https://doi.org/10.1007/BF00953179

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