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Halogenation of 3,6-di-tert-butylpyrocatechol with retention of the alkyl substituents

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    3,6-Di-tert-butylpyrocatechol can be brominated and chlorinated with retention of the tert-butyl groups.

  2. 2.

    The yield of the 4-bromo-3,6-di-tert-butylpyrocatechol that is formed during bromination is quite dependent on the nature of the solvent and the character of the counterion in the composition of the intermediate σ complex.

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Literature cited

  1. N. A. Azatyan, G. V. Karpukhina, I. S. Belostotskaya, and N. L. Komissarova, Neftekhimiya,13, 435 (1973).

    Google Scholar 

  2. I. S. Belostotskaya, N. L. Komissarova, V. B. Vol'eva, and V. V. Ershov, Transactions of Third All-Union Conference on the Degradation and Stabilization of Polymers [in Russian], Moscow (1977).

  3. I. S. Belostotskaya, É. V. Dzhuaryan, and V. V. Ershov, Izv. Akad. Nauk SSSR, Ser. Khim., 1100 (1977).

  4. I. A. Novikova, V. B. Vol'eva, N. L. Komissarova, I. S. Belostotskaya, and V. V. Ershov, Izv. Akad. Nauk SSSR, Ser. Khim., 2110 (1981).

  5. V. B. Vol'eva, I. A. Novikova, I. S. Belostotskaya, N. L. Komissarova, and V. V. Ershov, Izv. Akad. Nauk SSSR, Ser. Khim., 2128 (1981).

  6. E. Grovenstein and D. Kilby, J. Am. Chem. Soc.,79, 2972 (1957).

    Google Scholar 

  7. E. Shilov and F. Weinstein, Nature,182, 1300 (1958).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    V. B. Vol'eva, I. A. Novikova, I. S. Belostotskaya, É. V. Dzhuaryan & V. V. Ershov

Authors
  1. V. B. Vol'eva
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  2. I. A. Novikova
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  3. I. S. Belostotskaya
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  4. É. V. Dzhuaryan
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  5. V. V. Ershov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1416–1419, June, 1983.

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Vol'eva, V.B., Novikova, I.A., Belostotskaya, I.S. et al. Halogenation of 3,6-di-tert-butylpyrocatechol with retention of the alkyl substituents. Russ Chem Bull 32, 1285–1288 (1983). https://doi.org/10.1007/BF00953176

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  • DOI: https://doi.org/10.1007/BF00953176

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