Skip to main content
SpringerLink
Log in

Hydrolysis of substituted 2-ethoxy-2-oxo-1-oxa-2-phosphoindans

  • Brief Communications
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    We synthesized a number of 2-ethoxy-2-oxo-1-oxa-2-phosphoindans with substituants in the benzene ring and studied their reactivity in neutral aqueous hydrolysis.

  2. 2.

    It was shown that the rate constant for the hydrolysis of the phosphoindans is highly sensitive to a change in their structure, which sensitivity is determined by the dual effect of the substituents on the reaction center.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Literature cited

  1. B. E. Ivanov and L. A. Valitova, Izv. Akad. Nauk SSSR, Ser. Khim., 1090 (1967).

  2. L. A. Khismatullina, L. A. Valitova, and B. E. Ivanov, USSR Patent No. 362,844, March 22, 1971; Byull. Izobret., No. 3, 52 (1973).

  3. A. Eberhard and F. H. Westheimer, J. Am. Chem. Soc.,87, 253 (1965).

    Google Scholar 

  4. B. E. Ivanov and L. A. Valitova, Izv. Akad. Nauk SSSR, Ser. Khim., 1087 (1967).

  5. B. E. Ivanov, L. A. Valitova, L. A. Khismatullina, and M. Sh. Yagfarova, Izv. Akad. Nauk SSSR, Ser. Khim., 2187 (1971).

  6. B. E. Ivanov, L. A. Valitova, L. A. Kudryavtseva, T. G. Bykova, K. A. Derstuganova, and E. I. Gol'dfarb, Izv. Akad. Nauk SSSR, Ser. Khim., 672 (1974).

  7. B. E. Ivanov, L. A. Valitova, T. G. Bykova, K. Kh. Khairullin, and L. A. Khismatullina, Monograph on Some Organic and Physical Chemistry Problems [in Russian], Kazan (1972), p. 61.

  8. B. A. Arbuzov, V. E. Bel'skii, A. O. Vizel', K. M. Ivanovskaya, and G. Z. Motygullin, Dokl. Akad. Nauk SSSR,176, 323 (1967).

    Google Scholar 

  9. C. H. Rochester, The Chemistry of the Hydroxyl Group, Vol. 1, Int. Publ., London-New York-Sydney-Toronto (1971), p. 327.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR, USSR

    V. E. Bel'skii, L. A. Kudryavtseva, K. A. Derstuganova, L. A. Valitova, T. G. Bykova & B. E. Ivanov

Authors
  1. V. E. Bel'skii
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. A. Kudryavtseva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. K. A. Derstuganova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. L. A. Valitova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. T. G. Bykova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. B. E. Ivanov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1410–1412, June, 1983.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bel'skii, V.E., Kudryavtseva, L.A., Derstuganova, K.A. et al. Hydrolysis of substituted 2-ethoxy-2-oxo-1-oxa-2-phosphoindans. Russ Chem Bull 32, 1279–1281 (1983). https://doi.org/10.1007/BF00953174

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00953174

Keywords

Search

Navigation