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Preparation and structure of iron carbidocarbonyl cluster [(C2H5)4N][Fe5RhC(CO)16]

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The thermolysis of the reaction products of Fe(CO)5 with sodium amalgam in diglyme under certain conditions leads directly to Na2[Fe5(CO)14]. The latter in diglyme solution exhibits a high reactivity toward metal carbonyls and their derivatives, and also toward electron-unsaturated organometallic compounds, forming octahedral heteronuclear clusters.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk

    V. E. Lopatin, N. M. Mikova & S. P. Gubin

  2. Institute of Chemistry and Chemical Technology, Siberian Branch, Academy of Sciences of the USSR, Krasnoyarsk

    V. E. Lopatin, N. M. Mikova & S. P. Gubin

Authors
  1. V. E. Lopatin
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  2. N. M. Mikova
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  3. S. P. Gubin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1407–1409, June, 1983.

The authors express their gratitude to Yu. L. Slovokhotov and Yu. T. Struchkov for valuable discussions and an x-ray structure study of the crystals.

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Lopatin, V.E., Mikova, N.M. & Gubin, S.P. Preparation and structure of iron carbidocarbonyl cluster [(C2H5)4N][Fe5RhC(CO)16]. Russ Chem Bull 32, 1276–1278 (1983). https://doi.org/10.1007/BF00953173

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  • DOI: https://doi.org/10.1007/BF00953173

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