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Reaction of aromatic nitro compounds with transition metal complexes. 2. Complexes of platinum(II) with aromatic nitro compounds: synthesis, properties, spectra, and structure

  • É. N. Izakovich
  • L. M. Kachapina
  • R. P. Shibaeva
  • M. L. Khidekel'
Organic Chemistry

Conclusions

  1. 1.

    Complexes of platinum(II) with aromatic nitro compounds of the general formula PtCl(DMSO)(C6H3NO2R), where R=H, Cl, CH3, were synthesized. Their electronic and IR spectra were measured and discussed. The catalytic activity of the complexes in the hydrogenation reaction of the aromatic nitro compounds was shown.

     
  2. 2.

    An x-ray investigation of the PtCl(DMSO)(C6H4NO2) complex was carried out, and it was shown that the platinum atom has a square planar coordination and forms a five-membered metallo-ring, which includes one of the oxygen atoms of the nitro group and a carbon of the benzene ring at the ortho position with reference to the nitro group.

     

Keywords

Oxygen Hydrogenation Benzene DMSO Platinum 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1983

Authors and Affiliations

  • É. N. Izakovich
    • 1
  • L. M. Kachapina
    • 1
  • R. P. Shibaeva
    • 1
  • M. L. Khidekel'
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSR, Chernogolovka BranchUSSR

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