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Alkylation of aminomethyl derivatives of primary phosphines

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Di(phenylaminomethyl)phenylphosphine, N,N-disubstituted-5-phenyl-1,3,5-diazaphosphorinanes, and 1,5-diaza-3, 7-diphosphacyclooctane, on treatment with excess alkyl halide, are alkylated only at the P atom. In the case of bis(diethylaminomethyl)phenylphosphine, addition occurs at both phosphorus and nitrogen.

  2. 2.

    Reaction of 1,3-di-p-tolyl-5-tolylaminomethyl-1,3,5-diazaphosphorinane with alkyl halides affords P alkylation products with one and two moles of alkylating agent.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR, USSR

    O. A. Erastov, G. N. Nikonov & B. A. Arbuzov

Authors
  1. O. A. Erastov
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  2. G. N. Nikonov
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  3. B. A. Arbuzov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1379–1384, June, 1983.

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Erastov, O.A., Nikonov, G.N. & Arbuzov, B.A. Alkylation of aminomethyl derivatives of primary phosphines. Russ Chem Bull 32, 1250–1254 (1983). https://doi.org/10.1007/BF00953167

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  • DOI: https://doi.org/10.1007/BF00953167

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