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Acylation of N,N′-bisalkylidenethylenediamine in polar media as a method for the synthesis of 2-R-N,N′-diacylimidazolidines

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The direction of the reaction of bisalkylidene- and bisbenzylidenethylenediamines with acid chlorides depends on the polarity of the solvent used.

  2. 2.

    Acylation of bisalkylidenethylenediamines and bisbenzylidenethylenediamines in highly polar media leads to the formation of 2-alkyl- and 2-aryl-substituted N,N′-diacylimidazolidines.

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Literature cited

  1. H. Breederveld, Rec. Trav. Chim.,79, 401 (1960).

    Google Scholar 

  2. H. Böhme and K. Hartke, Chem. Ber.,96, 600 (1963).

    Google Scholar 

  3. J. P. Chupp and E. R. Weiss, J. Org. Chem.,33, 2357 (1968).

    Google Scholar 

  4. H. Bauer, J. Org. Chem.,26, 1649 (1961).

    Google Scholar 

  5. R. R. Mod, F. C. Mange, G. Sumrell, A. F. Novak, and J. M. Solar, US Patent No. 448427 (1974): Chem. Abstr.,82, 57725 (1975).

    Google Scholar 

  6. K. Negoro, T. Takemoto, H. Ozaki, and S. Oka, Hiroshima Daigaku, Kogakubu Kenkyu Hokoku,26, 9 (1977); Chem. Abstr.,88, 136527b (1978).

    Google Scholar 

  7. R. R. Mod, F. C. Mange, G. Sumrell, A. F. Novak, and J. M. Solar, US Patent No. 448425 (1974); Chem. Abstr.,82, 73023n (1975).

    Google Scholar 

  8. R. R. Mod, F. C. Mange, and G. Sumrell, J. Am. Oil. Chem. Soc.,48, No. 5, 254 (1971).

    Google Scholar 

  9. W. S. Emerson, S. M. Hess, and F. C. Uhle, J. Am. Chem. Soc,63, 872 (1941).

    Google Scholar 

  10. T. M. Patrick, J. Am. Chem. Soc.,74, 2984 (1952).

    Google Scholar 

  11. R. E. Brooks, US Patent 2,416,042 (1947); Chem. Abstr.,41, 3481c (1947).

    Google Scholar 

  12. F. Devinsky, I. Lacko, and L. Krasnec, Synthesis,4, 303 (1980).

    Google Scholar 

  13. P. F. Epstein, J. Org. Chem.,24, 68 (1959).

    Google Scholar 

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    G. Ya. Kondrat'eva, N. E. Agafonov & V. S. Bogdanov

Authors
  1. G. Ya. Kondrat'eva
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  2. N. E. Agafonov
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  3. V. S. Bogdanov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1359–1364, June, 1983.

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Kondrat'eva, G.Y., Agafonov, N.E. & Bogdanov, V.S. Acylation of N,N′-bisalkylidenethylenediamine in polar media as a method for the synthesis of 2-R-N,N′-diacylimidazolidines. Russ Chem Bull 32, 1231–1235 (1983). https://doi.org/10.1007/BF00953163

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  • DOI: https://doi.org/10.1007/BF00953163

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