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13C NMR spectra of parent hexopyranoses

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The13C NMR spectra were obtained and interpreted for aqueous solutions of three parent hexoses: D-talose, D-gulose, and L-idose. The parameters of the PMR spectra for solutions of these compounds in D2O are given.

  2. 2.

    The13C NMR spectra of the L-idose derivatives in aqueous solutions were interpreted for 6-deoxy- and 6-O-methyl-L-idose.

  3. 3.

    The dependence of the13C chemical shifts and\(^1 J_{1_H 1 - 13_C 1} \) spin-spin coupling constants in eight parent hexopyranoses on the position of the conformational equilibrium of the pyranose rings in solutions is discussed.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    A. S. Shashkov

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  1. A. S. Shashkov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1328–1336, June, 1983.

The author conveys his gratitude to A. F. Sviridov for the synthesis of L-idose and its derivatives.

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Shashkov, A.S. 13C NMR spectra of parent hexopyranoses. Russ Chem Bull 32, 1200–1207 (1983). https://doi.org/10.1007/BF00953157

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  • DOI: https://doi.org/10.1007/BF00953157

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