Conclusions
PMR spectroscopy and x-ray crystallographic structure analysis were used to study the structure of 4-nitro-3-methyl-1,1-diphenyl-1-sila-2-cyclopentene. The five-membered organosilicon heterocycle in the compound has envelope conformation with a ring flexure angle of 17.7°. A coordination interaction of the silicon atom with the NO2 group is excluded. The structural parameters do not indicate any additional interaction of silicon with the double bond.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1319–1325, June, 1983.
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D'yachenko, O.A., Sokolova, Y.A., Berestovitskaya, V.M. et al. Structure of 4-nitro-3-methyl-1,1-diphenyl-1-sila-2-cyclopentene. Russ Chem Bull 32, 1191–1196 (1983). https://doi.org/10.1007/BF00953155
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DOI: https://doi.org/10.1007/BF00953155