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Crystalline and molecular structure of the E,E,Z-isomer of 1-(4-nitrophenyl)-3,5,5-triphenylformazan

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    An x-ray diffraction study of low-polar forms of 1-(4-nitrophenyl)-3,5,5-triphenylformazan (Ia) was carried out.

  2. 2.

    It was found that (Ia) has the structure of an E1,2E2,3Z3,4-isomer with a planar formazan group, determining the extended conjugation chain in the molecule.

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Literature cited

  1. B. I. Buzykin, N. G. Gazetdinova, S. A. Flegontov, A. P. Stolyarov, and Yu. P. Kitaev, Zh. Org. Khim.,13, 1947 (1977).

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  2. B. I. Buzykin, V. D. Cherepinskii-Malov, I. A. Litvinov, N. G. Gazetdinova, and Yu. T. Struchkov, Izv. Akad. Nauk SSSR, Ser. Khim., 1306 (1982).

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR, USSR

    I. A. Litvinov, Yu. T. Struchkov, N. G. Gazetdinova & B. I. Buzykin

  2. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    I. A. Litvinov, Yu. T. Struchkov, N. G. Gazetdinova & B. I. Buzykin

Authors
  1. I. A. Litvinov
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  2. Yu. T. Struchkov
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  3. N. G. Gazetdinova
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  4. B. I. Buzykin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1303–1308, June, 1983.

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Litvinov, I.A., Struchkov, Y.T., Gazetdinova, N.G. et al. Crystalline and molecular structure of the E,E,Z-isomer of 1-(4-nitrophenyl)-3,5,5-triphenylformazan. Russ Chem Bull 32, 1177–1181 (1983). https://doi.org/10.1007/BF00953152

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  • DOI: https://doi.org/10.1007/BF00953152

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