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Influence of cyclization of N,N′-ethylenediaminedisuccinic acid on its complex-forming properties

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study has been made of the conditions for the occurrence of strucutral rearrangement when an aqueous solution of N,N′-ethylenediaminedisuccinic acid is heated in acid; this chelating agent, like other analogs of ethylenediaminediacetic acid, undergoes intramolecular cyclization, with a substantial decrease in its complex-forming properties.

  2. 2.

    The hypothesis advanced in the literature that the chelating agent is decarboxvlated is not in accord with the facts.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1293–1299, June, 1983.

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Kolleganov, M.Y., Kolleganova, I.G., Mitrofanova, N.D. et al. Influence of cyclization of N,N′-ethylenediaminedisuccinic acid on its complex-forming properties. Russ Chem Bull 32, 1167–1172 (1983). https://doi.org/10.1007/BF00953150

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  • DOI: https://doi.org/10.1007/BF00953150

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