Skip to main content
SpringerLink
Log in

Photochemical interaction of phosphine hydride complexes of molybdenum and tungsten with carbon monoxide

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Irradiation of phosphine hydride complexes MH4L4, where M=Mo or W and L=PMePh2 or 1/2(Ph2PCH2)2, in a CO atmosphere leads to successive replacement of the hydride and phosphine ligands by carbonyl, forming M(CO)xL6−x (x=2, 3, 4, 5). The degree of substitution x depends on the nature of the metal M and ligand L and on the length of the irradiation period. The rate of photochemical interaction of MH4L4, with CO is approximately two orders of magnitude greater than the rate of the analogous dark reaction.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. A. P. Pivovarov, Yu. V. Gak, Yu. M. Shul'ga, V. D. Makhaev, A. P. Borisov, and Yu. G. Borod'ko, Izv. Akad. Nauk SSSR, Ser. Khim., 2590 (1979).

  2. A. P. Pivovarov, Yu. V. Gak, Yu. M. Shul'ga, V. D. Makhaev, A. P. Borisov, and Yu. G. Borod'ko, Izv. Akad. Nauk SSSR, Ser. Khim., 918 (1981).

  3. A. P. Pivovarov, Yu, V. Gak, T. N. Doronina, V. D. Makhaev, A. P. Borisov, and Yu. G. Borod'ko, Izv. Akad. Nauk SSSR, Ser, Khim., 1207 (1981).

  4. A. P. Pivovarov, Yu. V. Gak, L. M. Ioffe, V. D. Makhaev, A. P. Borisov, and Yu. G. Borod'ko, 14th All-Union Chugaev (Tschugaeff) Conference on the Chemistry of Comnlex Compounds [Summaries of Papers) [in Russian], Ivanovo (1981), Part II, p. 566.

  5. A. P. Borisov, V. D. Makhaev, and K. N. Semenenko, Koord. Khim.,5, 948 (1979).

    Google Scholar 

  6. V. D. Makhaev, A. P. Borisov, and K. N. Semenenko, Koord. Khim.,6, 260 (1980).

    Google Scholar 

  7. V. D. Makhaev, A. P. Borisov, N. G. Mozgina, G. N. Boiko, and K. N. Semenenko, Izv. Akad. Nauk SSSR, Ser. Neorg. Mater.,14, 1726 (1978).

    Google Scholar 

  8. J. Chatt and H. R. Watson, J. Chem. Soc., 4980 (1961).

  9. S. Datta, T. J. McNeese, and S. S. Wreford, Inorg. Chem.,16, 2661 (1977).

    Google Scholar 

  10. T. A. George and C. D. Seibold, Inorg. Chem.,12, 2548 (1973).

    Google Scholar 

  11. S. O. Grim, D. A. Wheatland, and W. McFarlane, J. Am. Chem. Soc.,89, 5573 (1967).

    Google Scholar 

  12. V. I. Losilkina, N. K. Baranetskaya, V. N. Setkina, and D. N. Kursanov, Koord. Khim.,5, 1816 (1979).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Branch of the Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka

    A. P. Pivovarov, Yu. V. Gak, L. M. Ioffe, A. P. Borisov & V. D. Makhaev

Authors
  1. A. P. Pivovarov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yu. V. Gak
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. M. Ioffe
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. P. Borisov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. D. Makhaev
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1289–1293, June, 1983.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Pivovarov, A.P., Gak, Y.V., Ioffe, L.M. et al. Photochemical interaction of phosphine hydride complexes of molybdenum and tungsten with carbon monoxide. Russ Chem Bull 32, 1163–1167 (1983). https://doi.org/10.1007/BF00953149

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00953149

Keywords

Search

Navigation