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Regulation of photochromic properties of fast-relaxing spiropyrans in polymer films

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

When an indoline spiropyran (SPP) with electron-donor substituents in the chromene part of the molecule is introduced into a polymer matrix, in particular into copolymers of methyl methacrylate with oxyethyl methacrylate, there is a decrease in the rate of reaction of dark decolorization of the photoinduced form of the SPP, owing to interaction of the proton-donor units of the oxyethyl methacrylate and the oxygen of the chromene heterocycle of the photoinduced form of the SPP molecule, leading to the formation of an intermolecular hydrogen bond.

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow

    G. M. Semyakina, T. G. Samedova, N. I. Popova, É. R. Zakhs, Ya. N. Malkin, V. P. Martynova, V. A. Barachevskii, D. A. Topchiev & V. A. Kabanov

Authors
  1. G. M. Semyakina
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  2. T. G. Samedova
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  3. N. I. Popova
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  4. É. R. Zakhs
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  5. Ya. N. Malkin
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  6. V. P. Martynova
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  7. V. A. Barachevskii
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  8. D. A. Topchiev
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  9. V. A. Kabanov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1277–1282, June, 1983.

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Semyakina, G.M., Samedova, T.G., Popova, N.I. et al. Regulation of photochromic properties of fast-relaxing spiropyrans in polymer films. Russ Chem Bull 32, 1153–1157 (1983). https://doi.org/10.1007/BF00953147

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  • DOI: https://doi.org/10.1007/BF00953147

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