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Joint adsorption of organic and water vapors on microporous carbonaceous adsorbents

I. Joint adsorption of cyclohexane and water vapors on activated carbon in equilibrium with moisture

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    We studied the joint adsorption of vapors of cyclohexane and water on activated carbon, equilibrated with moisture.

  2. 2.

    The amounts of adsorption of cyclohexane determined in experiments at equilibrium relative humidities of water vapor do not depend on the amount of preadsorbed water responsible for the adsorption or desorption branches of the isotherm.

  3. 3.

    For identical contents of preadsorbed water, but with different equilibria with relative humidities, corresponding to the adsorption and desorption branches of the isotherm, the adsorption curves and the values for adsorption of cyclohexane differ significantly from each other.

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Literature cited

  1. M. M. Dubinin, Izv. Akad. Nauk SSSR, Ser. Khim., 9 (1981).

  2. B. P. Bering and V. V. Serpinskii, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 1186 (1959).

  3. M. M. Dubinin, K. M. Nikolaev, N. S. Polyakov, and G. L. Pirozhkov, Izv. Akad. Nauk SSSR, Ser. Khim., 1487 (1980).

  4. M. M. Dubinin, V. S. Kut'kov, A. V. Larin, K. M. Nikolaev, and N. S. Polyakov, Zh. Fiz. Khim.,56, 985 (1982).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1231–1235, June, 1983.

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Dubinin, M.M., Kut'kov, V.S., Larin, A.V. et al. Joint adsorption of organic and water vapors on microporous carbonaceous adsorbents. Russ Chem Bull 32, 1111–1114 (1983). https://doi.org/10.1007/BF00953137

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  • DOI: https://doi.org/10.1007/BF00953137

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