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Fluorination of perfluoroallyl fluosulfate

  • V. F. Cherstkov
  • S. R. Sterlin
  • L. S. German
  • E. M. Kagramanova
  • I. L. Knunyants
Brief Communications
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Conclusions

The fluorination of perfluoroallyl fluosulfate at −78° leads to the formation of a mixture of 1,4-bis-fluorosulfonyloxyperfluoro-2,3-dimethylbutane (II), 1,5-bis-fluorosulfonyloxyperfluoro-2-methylpentane (III), and 1,6-bis-fluorosulfonyloxyperfluorohexane (IV). The treatment of a mixture of (II)-(IV) with CsF gave a mixture of the acid fluorides of the perfluorodimethylsuccinic, perfluoro-2-methylglutaric, and perfluoroadipic acids.

Keywords

Fluoride Acid Fluoride Dimethylbutane Perfluoroallyl Fluosulfate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Literature cited

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    W. T. Miller, J. Fluor. Chem.,18, 305 (1981).Google Scholar
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    H. G. Horn, Chem. Ztg.,95, 893 (1971).Google Scholar
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    S. Nagase, J. Synth. Org. Chem. Jpn.,31, 441 (1973).Google Scholar
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    I. J. Hotchkins, R. Stephens, and J. C. Tatlow, J. Fluor. Chem.,85, 379 (1976).Google Scholar
  5. 5.
    C. G. Krespan and D. C. England, J. Am. Chem. Soc.,103, 598 (1981).Google Scholar

Copyright information

© Plenum Publishing Corporation 1983

Authors and Affiliations

  • V. F. Cherstkov
    • 1
  • S. R. Sterlin
    • 1
  • L. S. German
    • 1
  • E. M. Kagramanova
    • 1
  • I. L. Knunyants
    • 1
  1. 1.A. N. Nesmeyanov Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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