Mechanism of the electrochemical reduction of Co(III) complexes with α-aminooximes
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A mechanism for the electrochemical reduction of Co (III) complexes withα-amino acids is proposed, which involves a stepwise acceptance of one and two electrons by the depolarizer molecule, accompanied by an incorporated chemical stage.
By means of the ESR and electrochemical methods it has been shown that the nature of this stage is the elimination of one or two inner sphere ligands after addition of the first electron, which makes the first stage of the electrode process irreversible in character.
KeywordsElectrochemical Method Electrochemical Reduction Electrode Process Chemical Stage Sphere Ligand
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