Intramolecular electron transfer in the intermediately formed radical-anion during electroreduction of ethyl 3,7-dimethyl-10-oxo-2,6-decadienoate in DMFA

  • S. G. Mairanovskii
  • G. K. Bishimbaeva
  • N. Ya. Grigor'eva
  • I. M. Avrutov
  • V. N. Odinokov
  • G. A. Tolstikov
Physical Chemistry
  • 15 Downloads

Conclusions

  1. 1.

    The polarographic behavior of the four isomers of ethyl 3,7-diraethyl-10-oxo-2,6-decadienoate and also of model compounds (heptenal and 2E,6Z-farnesenic ester) was studied. During electroreduction intramolecular electron transfer from the ester groups to the aldehyde group occurs in the intermediately formed radical-anion.

     
  2. 2.

    The existence of the conformation with closer aldehyde and carboxyl groups in the α,ω-aldehydo esters (I) was confirmed by the polarographic method.

     

Keywords

Ester Ethyl Aldehyde Carboxyl Electron Transfer 

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Literature cited

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Copyright information

© Plenum Publishing Corporation 1986

Authors and Affiliations

  • S. G. Mairanovskii
    • 1
    • 2
  • G. K. Bishimbaeva
    • 1
    • 2
  • N. Ya. Grigor'eva
    • 1
    • 2
  • I. M. Avrutov
    • 1
    • 2
  • V. N. Odinokov
    • 1
    • 2
  • G. A. Tolstikov
    • 1
    • 2
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow
  2. 2.Institute of Chemistry, Bashkir BranchAcademy of Sciences of the USSRUfa

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