Radical polymerization of N,N-diallyl quaternary salts in the presence of uranyl ions

  • N. A. Golubkova
  • A. I. Martynenko
  • N. A. Babaev
  • A. V. Nechaeva
  • A. A. Éfendiev
  • D. A. Topchiev
  • V. A. Kabanov
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Conclusions

  1. 1.

    The presence of uranyl ions in an aqueous solution of N,N-diallyl-N-isopropoxycarbonylmethyl-N-methylammonium chloride (DIMC) markedly accelerates the photoinitiated radical polymerization of this salt.

     
  2. 2.

    The initial polymerization rate is increased by a factor of up to 20 upon increasing the initial uranyl ion concentration in aqueous solutions of the monomer containing ammonium peroxydisulfate. The dependence of the initial polymerization rate and of the specific viscosity of the polymer formed on the UO22+/DIMC mole ratio passes through a maximum.

     

Keywords

Polymerization Viscosity Chloride Ammonium Aqueous Solution 

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Literature cited

  1. 1.
    M. Fred Gouver, J. Macromol. Sci. Chem., Ser. A4,6, 1327 (1970).Google Scholar
  2. 2.
    S. E. Bresler and B. L. Erusalimskii, The Physics and Chemistry of Macromolecules [in Russian], Nauka, Moscow-Leningrad (1965), p. 218.Google Scholar
  3. 3.
    N. A. Babaev, A. I. Martynenko, V. D. Oppengeim, A. M. Krapivin, A. A. Éfendiev, and D. A. Topchiev, Azerb. Khim. Zh., No. 4, 89 (1983).Google Scholar
  4. 4.
    É. M. Battalov, S. I. Kuznetsova, V. E. Karasev, V. S. Kolosnitsyn, G. V. Leplyanin, and S. R. Rafikov, Transactions of the Fifth International Microsymposium on Radical Polymerization [in Russian], Ufa (1984), p. 25.Google Scholar
  5. 5.
    V. Amirthalingam, D. V. Chaudram, and V. M. Padmanabham, Acta Crystallogr.,12, 821 (1959).Google Scholar

Copyright information

© Plenum Publishing Corporation 1986

Authors and Affiliations

  • N. A. Golubkova
    • 1
  • A. I. Martynenko
    • 1
  • N. A. Babaev
    • 1
  • A. V. Nechaeva
    • 1
  • A. A. Éfendiev
    • 1
  • D. A. Topchiev
    • 1
  • V. A. Kabanov
    • 1
  1. 1.A. V. Topchiev Institute of Petrochemical SynthesisAcademy of Sciences of the USSRMoscow

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