Reaction of hypochlorous acid with 2,6-di-tert-butylphenol and its derivatives

  • G. F. Bannikov
  • V. B. Vol'eva
  • G. A. Nikiforov
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Conclusions

Regioselectivity was established for the chlqrination of sterically hindered phenols by HOCl. The direction of chlorination is dependent on the temperature, acidity of the medium, and electronic effect of the para substituent.

Keywords

Phenol Acidity HOCl Electronic Effect Hypochlorous Acid 

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Literature cited

  1. 1.
    V. V. Ershov, G. A. Nikiforov, and A. A. Volod'kin, Sterically Hindered Phenols [in Russian], Khimiya, Moscow (1972), pp. 63, 67, 261.Google Scholar
  2. 2.
    L. Denivelle and M. Hedayatullan, Comptes Rendus Acad. Sci.,253, 23, 2711 (1961).Google Scholar
  3. 3.
    G. A. Nikiforov, A. A. Volod'kin, and K. M. Dyumaev, Izv. Akad. Nauk SSSR, Ser. Khim., 1661 (1963).Google Scholar

Copyright information

© Plenum Publishing Corporation 1986

Authors and Affiliations

  • G. F. Bannikov
    • 1
  • V. B. Vol'eva
    • 1
  • G. A. Nikiforov
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRMoscow

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