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Preparation and reactivity of metal-containing monomers. Communication 2. Radiation graft polymerization of allyl alcohol complexed on polyethylene

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study of the postradiation graft polymerization of complexed allyl alcohol was carried out for the first time. Copolymers were obtained containing up to 2.4 mass % polyallyl alcohol and 2.4 mass % metal.

  2. 2.

    The grafting rate is constant for several hours and increases with an increase in the concentration of the complexing agent in the reaction mixture up to [CoCl2]:[AA] mole ratio equal to 1∶5.

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Literature cited

  1. C. E. Schildknecht, Allyl Compounds and Their Polymers, Wiley Interscience, New York (1973), p. 201.

    Google Scholar 

  2. V. F. Kornil'eva, M. N. Masterova, E. S. Garina, V. P. Zubov, V. A. Kabanov, L. S. Polak, and V. A. Kargin, Vysokomol. Soedin.,A13, 1830 (1971).

    Google Scholar 

  3. L. I. Ganzyuk, L. S. Stepanova, and L. S. Chernysheva, Vysokomol. Soedin.,B18, 101 (1976).

    Google Scholar 

  4. D. A. Kritskaya, A. D. Pomogailo, A. N. Ponomarev, and F. S. D'yachkovskii, Vysokomol. Soedin.,A21, 1107 (1979).

    Google Scholar 

  5. N. A. Platé, L. I. Valuev, M. N. Masterova, and A. P. Istomin, USSR Inventor's Certificate No. 608,813; Byull. Izobret., No. 20, 73 (1978).

  6. Sh. A. Kurbanov, B. Sh.Khakimdzhanov, U. N. Musaev, and R. S. Tillaev, Sbor. Nauchn. Trudov Tashkentsk. Gos. Univ., No. 498, 26 (1975).

    Google Scholar 

  7. K. Sone, Y. Fukuda, J. Mizusaki, and K. Moriyama, Monatsch. Chem.,107, 271 (1976).

    Google Scholar 

  8. S. A. Dolmatov and L. S. Polak, Neftekhimiya,3, 683 (1963).

    Google Scholar 

  9. D. A. Kritskaya, A. D. Pomogailo, A. N. Ponomarev, and F. S. D'yachkovskii (Dyachkovskii), J. Appl. Polym. Sci.,25, 349 (1980).

    Google Scholar 

  10. Yu. N. Grigor'ev, V. S. Savost'yanov, D. A. Kritskaya, A. N. Ponomarev, and P. A. Zagorets, Vysokomol. Soedin.,A24, 1765 (1982).

    Google Scholar 

  11. V. S. Savost'yanov, D. A. Kritskaya, and A. N. Ponomarev, Vysokomol. Soedin.,B27, 66 (1985).

    Google Scholar 

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Authors and Affiliations

  1. Division of the Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka

    V. S. Savost'yanov, A. D. Pomogailo, D. A. Kritskaya & A. N. Ponomarev

Authors
  1. V. S. Savost'yanov
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  2. A. D. Pomogailo
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  3. D. A. Kritskaya
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  4. A. N. Ponomarev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 42–44, January, 1986.

The authors express their gratitude to I. N. Ivleva and S. B. Echmaev for carrying out the magnetic studies.

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Savost'yanov, V.S., Pomogailo, A.D., Kritskaya, D.A. et al. Preparation and reactivity of metal-containing monomers. Communication 2. Radiation graft polymerization of allyl alcohol complexed on polyethylene. Russ Chem Bull 35, 33–35 (1986). https://doi.org/10.1007/BF00952840

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  • DOI: https://doi.org/10.1007/BF00952840

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