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IR spectral study of di(trifluoroacet)amide

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Di(trifluoroacet)amide, (CF3CO)2NH, in the gaseous state and in solutions of inert solvents exist predominantly in the monomeric trans-trans form.

  2. 2.

    Monomeric diacetamide, (MeCO)2NH, converts from the cis-trans form to the more polar trans-trans form with increasing polarity of the dielectric constant of the medium. The cyclic dimers of the cis-trans form in CH2Cl2 convert to linear trans-trans polyaggregates with decreasing temperature.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2852–2854, December, 1988.

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Chipanina, N.N., Shulunova, A.M., Yushmanova, T.I. et al. IR spectral study of di(trifluoroacet)amide. Russ Chem Bull 37, 2574–2576 (1988). https://doi.org/10.1007/BF00952647

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  • DOI: https://doi.org/10.1007/BF00952647

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