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Nature of the induction period in the chemiluminescent reaction of W(CO)6 and XeF2

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The length of the induction period of the reaction of W(CO)6 and XeF2 in toluene is proportional to the reagent concentrations and temperature.

  2. 2.

    Only WF6 among the various products (CO2, C, HF, Xe, and WF6) accelerated the reaction. The presence of water in toluene inhibits this reaction due its reaction with WF6.

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Literature cited

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Authors and Affiliations

  1. Institute of Chemistry, Bashkir Science Center, Urals Branch, Academy of Sciences of the USSR, Ufa

    R. G. Bulgakov, S. P. Kuleshov, G. A. Tolstikov & V. P. Kazakov

Authors
  1. R. G. Bulgakov
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  2. S. P. Kuleshov
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  3. G. A. Tolstikov
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  4. V. P. Kazakov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2842–2844, December, 1988.

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Bulgakov, R.G., Kuleshov, S.P., Tolstikov, G.A. et al. Nature of the induction period in the chemiluminescent reaction of W(CO)6 and XeF2 . Russ Chem Bull 37, 2565–2567 (1988). https://doi.org/10.1007/BF00952642

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  • DOI: https://doi.org/10.1007/BF00952642

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