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Synthesis of C1-C4 hydrocarbons from CO and H2 on cobalt carbonyl zeolite catalysts

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Catalysts obtained by the decomposition of Co(NO)(CO)3 on zeolite sodium forms display activity in the synthesis of C1-C4 hydrocarbons from CO and H2 at 220–260°C and atmospheric pressure. The catalysts may be arranged in the following series relative to decreasing specific activity: Co/NaM > Co/ZHM ≈ Co/NaA > Co/NaY > Co/NaX.

  2. 2.

    Cobalt on the external surface of zeolites participates to a greater content in the formation of the active sites for the synthesis of hydrocarbons from CO and H2.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    A. L. Lapidus, M. M. Savel'ev, M. V. Tsapkina & Kh. M. Minachev

Authors
  1. A. L. Lapidus
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  2. M. M. Savel'ev
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  3. M. V. Tsapkina
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  4. Kh. M. Minachev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2836–2839, December, 1988.

The authors express their gratitude to P. I. Slyunyaev for the determination of cobalt in the catalysts.

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Lapidus, A.L., Savel'ev, M.M., Tsapkina, M.V. et al. Synthesis of C1-C4 hydrocarbons from CO and H2 on cobalt carbonyl zeolite catalysts. Russ Chem Bull 37, 2560–2562 (1988). https://doi.org/10.1007/BF00952640

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  • DOI: https://doi.org/10.1007/BF00952640

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