Skip to main content
Log in

Free-radical addition of alkanals to acrolein diacetate

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The free-radical addition of alkanals to acrolein diacetate constitutes an efficient one-step method for the synthesis of 1,1-diacetoxyalkan-4-ones.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. General Organic Chemistry [in Russian], Vol. 2, Khimiya, Moscow (1982), pp. 637, 642, 649.

  2. R. A. Ellison, Synthesis, 397 (1973).

  3. O. G. Kulinkovich, I. G. Tishchenko [Tischenko], and V. L. Sorokin, Zh. Org. Khim.,20, 2548 (1984); O. G. Kulinkovich, I. G. Tishchenko, and N. V. Masalov, Synthesis, 886 (1984); O. G. Kulinkovich, I. G. Tishchenko, and V. L. Sorokin, Synthesis, 1058 (1985).

    Google Scholar 

  4. J. Stowell, J. Org. Chem.,41, 560 (1976).

    Google Scholar 

  5. M. Mikolajczyk and A. Midura, Nouv. J. Chim.,10, 567 (1986).

    Google Scholar 

  6. M. C. Mussato, D. Savoia, C. Trombini, and A. Umani-Ronchi, J. Org. Chem.,45, 4002 (1980); D. Savoia, C. Trombini, and A. Umani-Ronchi, J. Org. Chem.,47, 564 (1982); C. Boga, D. Savoia, C. Trombini, and A. Umani-Ronchi, Synthesis, 212 (1986).

    Google Scholar 

  7. K. Kondo and D. Tunemoto, Tetrahedron Lett., 1397 (1975).

  8. T. Yoshida, T. Miyakoshi, and S. Saito, Yukagaku,33, 628 (1984).

    Google Scholar 

  9. E. Wenkert, B. L. Buckwalter, and A. A. Craveiro, J. Am. Chem. Soc.,100, 1267 (1978).

    Google Scholar 

  10. U. Valcavi, P. Farina, S. Innocenti, and V. Marotta, Synthesis, 124 (1983).

  11. K. S. Kochhar, B. S. Bal, R. P. Deshpande, et al., J. Org. Chem.,48, 1765 (1983).

    Google Scholar 

  12. Rearrangements in Ground and Excited States, Academic Press, New York (1980), Vol. 1, p. 241.

  13. J. K. Michie and J. A. Miller, Synthesis, 824 (1981).

  14. L. Fieser and M. Fieser, Reagents for Organic Synthesis, 3 Vols., Wiley, New York (1967).

    Google Scholar 

  15. V. Karnozhitskii, Organic Peroxides [Russian translation], IL, Moscow (1961), p. 58.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2813–2815, December, 1988.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ogibin, Y.N., Molokanov, A.N. & Nikishin, G.I. Free-radical addition of alkanals to acrolein diacetate. Russ Chem Bull 37, 2536–2538 (1988). https://doi.org/10.1007/BF00952634

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00952634

Keywords

Navigation