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1H and13C NMR spectral study of the structural effects of substituents in N-vinyl-2-arylpyrroles

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Alterations of the dihedral angles between the planes of the three unsaturated fragments are interrelated in N-vinyl-2-arylpyrroles. Upon the introduction of a substituent at C3 in the pyrrole ring, the dihedral angle between the planes of the aryl and pyrrole ring increases, while the corresponding angle between the planes of the vinyl group and pyrrole ring decreases.

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Literature cited

  1. A. V. Afonin, M. V. Sigalov, V. K. Voronov, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 1418 (1987).

  2. A. V. Afonin, V. K. Voronov, L. A. Es'kova, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 202 (1987).

  3. A. V. Afonin, V. K. Voronov, A. I. Mikhaleva, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 184 (1987).

  4. M. V. Sigalov, G. A. Kalabin, A. I. Mikhaleva, and B. A. Trofimov, Khim. Geterotsikl. Soedin., 328 (1980).

  5. E. Kolehmainen, R. Laatikainen, and V. Kral, Magn. Reson. Chem.,24, 498 (1986).

    Google Scholar 

  6. B. I. Ionin, B. A. Ershov, and A. I. Kol'tsov, NMR Spectroscopy in Organic Chemistry [in Russian], Izd. Khimiya, Leningrad (1983), p. 27.

    Google Scholar 

  7. K. Tsutsui, K. Hirotsu, M. Umesaki, et al., Acta Crystallogr.,B32, 3049 (1976).

    Google Scholar 

  8. J. E. Almlof, Chem. Phys. Lett.,26, 215 (1974).

    Google Scholar 

  9. M. V. Sigalov, B. A. Shainyan, G. A. Kalabin, et al., Khim. Geterotsikl. Soedin., 627 (1980).

  10. C. W. Fong and H. G. Grant, Austr. J. Chem.,34, 957 (1981).

    Google Scholar 

  11. P. E. Hansen, Progr. NMR Spectrosc.,14, 175 (1981).

    Google Scholar 

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR

    A. V. Afonin, M. V. Sigalov, S. E. Korostova, V. K. Voronov & I. A. Aliev

Authors
  1. A. V. Afonin
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  2. M. V. Sigalov
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  3. S. E. Korostova
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  4. V. K. Voronov
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  5. I. A. Aliev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2765–2769, December, 1988.

The authors express their gratitude to V. K. Turchanin for a useful discussion of these results.

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Afonin, A.V., Sigalov, M.V., Korostova, S.E. et al. 1H and13C NMR spectral study of the structural effects of substituents in N-vinyl-2-arylpyrroles. Russ Chem Bull 37, 2490–2494 (1988). https://doi.org/10.1007/BF00952625

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  • DOI: https://doi.org/10.1007/BF00952625

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