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Effect of oxygen on the chemiluminescence during the oxidation of ethylaluminum diethoxide by xenon difluoride in solution

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The effect of oxygen on the chemiluminescent reaction of alkyl organoaluminum compounds with xenon difluoride was determined. The emission becomes stronger or weaker depending on the concentration of oxygen in the solution.

  2. 2.

    In addition to the main source of emission (reactions not containing O2 radicals), there is an additional source due to the transformation of the alkyl radicals (reaction intermediates) into peroxyl radicals, which disproportionate with the emission of light.

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Literature cited

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Authors and Affiliations

  1. Institute of Chemistry, Bashkir Scientific Center, Urals Branch, Academy of Sciences of the USSR, Ufa

    R. G. Bulgakov, V. N. Yakovlev, G. Ya. Maistrenko, G. A. Tolstikov & V. P. Kazakov

Authors
  1. R. G. Bulgakov
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  2. V. N. Yakovlev
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  3. G. Ya. Maistrenko
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  4. G. A. Tolstikov
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  5. V. P. Kazakov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2732–2736, December, 1988.

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Bulgakov, R.G., Yakovlev, V.N., Maistrenko, G.Y. et al. Effect of oxygen on the chemiluminescence during the oxidation of ethylaluminum diethoxide by xenon difluoride in solution. Russ Chem Bull 37, 2458–2462 (1988). https://doi.org/10.1007/BF00952618

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  • DOI: https://doi.org/10.1007/BF00952618

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