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Palladium catalysts on carbon supports

1. General features of adsorption of H2PdCl4 on carbon supports
  • P. A. Simonov
  • V. A. Semikolenov
  • V. A. Likholobov
  • A. I. Boronin
  • Yu. I. Ermakov
Physical Chemistry
  • 28 Downloads

Conclusions

  1. 1.

    The reaction of H2PdCl4 with carbon supports results in the formation of chloride complexes of Pd(II) with adsorption sites located on the unoxidized sections of the surface.

     
  2. 2.

    At least three types of H2PdCl4 adsorption sites which differ in the strength of the complexes with Pd(II) formed and the reactivity to the effect of oxidants were found. It was hypothesized that the elements of the π system of the carbon support are the adsorption sites of Pd(II).

     

Keywords

Chloride Palladium Adsorption Site Carbon Support Palladium Catalyst 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1989

Authors and Affiliations

  • P. A. Simonov
    • 1
  • V. A. Semikolenov
    • 1
  • V. A. Likholobov
    • 1
  • A. I. Boronin
    • 1
  • Yu. I. Ermakov
    • 1
  1. 1.Institute of Catalysis, Siberian BranchAcademy of Sciences of the USSRNovosibirsk

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