Skip to main content
SpringerLink
Log in

Characteristics of rheniecene hydride in hydrogenation reactions

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A catalyst obtained from rheniecene hydride (η5-C5H5)2ReH at 180–230°C and under a pressure of 10 MPa, is highly active in the hydrogenation of cyclohexene, benzene, and ethyl acetate.

  2. 2.

    An activity series was obtained of the heterometallic complexes based on rheniecene hydride in the hydrogenation of acetic acid: (C5H5)2ReH > (C5H5)2ReH·AlCl3 > (C5H5)2-ReH·AlHCl2 > (C5H5)2ReH·AlBr3.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. M. A. Ryashentseva and Kh. M. Minachev, Rhenium and Its Compounds in Heterogeneous Catalysis [in Russian], Nauka, Moscow (1983), p. 247.

    Google Scholar 

  2. B. R. James, Homogeneous Hydrogenation, Wiley, New York (1973).

    Google Scholar 

  3. M. A. Green, J. C. Huffman, K. G. Coulton, et al., J. Organomet. Chem.,218, No. 2, 39 (1981).

    Google Scholar 

  4. M. A. Ryashentseva, Kh. M. Minachev, V. M. Ishchenko, and B. M. Bulychev, Inventor's Certificate No. 1,132,968 (USSR); Byull. Izobret., No. 1, 33 (1985).

  5. V. M. Ishchenko, Candidate of Chemical Sciences Dissertation, Moscow State University, Moscow (1984).

    Google Scholar 

  6. M. L. H. Green, L. Praft, and G. Wilkinson, J. Chem. Soc., 3916 (1958).

  7. M. A. Ryashentseva, Kh. M. Minachev, V. V. Dorogov, and N. S. Prostakov, Khim. Geterotsikl. Soedin., 88 (1972).

  8. M. A. Ryashentseva, E. P. Belanova, and Kh. M. Minachev, Izv. Akad. Nauk SSSR, Ser. Khim., 2756 (1978).

  9. Kh. M. Minachev, V. I. Avaev, and M. A. Ryashentseva, Izv. Akad. Nauk SSSR, Ser. Khim., 306 (1986).

  10. M. A. Ryashentseva, E. P. Belanova, and Kh. M. Minachev, Neftekhimiya,22, No. 2, 231 (1982).

    Google Scholar 

  11. H. S. Broadbent and W. J. Bartley, J. Org. Chem.,28, 2345 (1963).

    Google Scholar 

  12. M. A. Ryashentseva, Kh. M. Minachev, and E. P. Belanova, Izv. Akad. Nauk SSSR, Ser. Khim., 1906 (1974).

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    M. A. Ryashentseva, Kh. M. Minachev, B. M. Bulychev & V. M. Ishchenko

  2. M. V. Lomonosov Moscow State University, USSR

    M. A. Ryashentseva, Kh. M. Minachev, B. M. Bulychev & V. M. Ishchenko

Authors
  1. M. A. Ryashentseva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Kh. M. Minachev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. B. M. Bulychev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. M. Ishchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2707–2710, December, 1988.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ryashentseva, M.A., Minachev, K.M., Bulychev, B.M. et al. Characteristics of rheniecene hydride in hydrogenation reactions. Russ Chem Bull 37, 2436–2439 (1988). https://doi.org/10.1007/BF00952612

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00952612

Keywords

Search

Navigation