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High-temperature organic synthesis

9. Thermal transformations of dimethyl sulfide and therane

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The pyrolytic transformations of dimethyl sulfide were studied in a flow system at 500–600°C. The liquid products of the pyrolysis of this compound are vinylthiol and thiophene. The yields and ratio of these products are determined by the temperature, ratio, and contact time of the starting reagents.

  2. 2.

    Thiirane undergoes greater pyrolytic conversion at 500°C than dimethyl sulfide and, in addition to vinylthiol and thiophene, forms benzothiophene.

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    É. N. Deryagin, É. N. Sukhomazova, O. B. Bannikova & M. G. Voronkov

Authors
  1. É. N. Deryagin
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  2. É. N. Sukhomazova
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  3. O. B. Bannikova
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  4. M. G. Voronkov
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Additional information

Communication 8 [1].

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2103–2105, September, 1979.

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Deryagin, É.N., Sukhomazova, É.N., Bannikova, O.B. et al. High-temperature organic synthesis. Russ Chem Bull 28, 1936–1938 (1979). https://doi.org/10.1007/BF00952482

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  • DOI: https://doi.org/10.1007/BF00952482

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