Conclusions
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1.
Bis(1-o-carboranyl)methane was synthesized by the reaction of 1-propargyl-o-carborane with decaborane.
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2.
The splitting of the stretching vibration bands of the CH bonds of the carborane nuclei was observed in the vibrational spectrum of bis(1-o-carboranyl)methane, which cannot be explained by either crystal effects or Fermi resonance.
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Literature cited
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L. A. Leites, L. E. Vinogradova, V. T. Aleksanyan, and S. S. Bukalov, Izv. Akad. Nauk SSSR, Ser. Khim.,1976, 2480.
L. E. Vinogradova, L. A. Leites, S. S. Bukalov, A. I. Kovredov, and L. I. Zakharkin, Izv. Akad. Nauk SSSR, Ser. Khim.,1977, 2337.
L. I. Zakharkin and N. F. Shemyakin, Izv. Akad. Nauk SSSR, Ser. Khim.,1977, 2350.
L. I. Zakharkin, A. I. Kovredov, Zh. S. Shaugumbekova, L. E. Vinogradova, and L. A. Leites, Zh. Obshch. Khim.,51, 1582 (1981).
L. I. Zakharkin and A. I. Kovredov, Izv. Akad. Nauk SSSR, Ser. Khim.,1973, 1428.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2170–2172, September, 1982.
The authors thank N. F. Shemyakin for supplying the sample of bis(1-o-carboranyl)methane.
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Leites, L.A., Vinogradova, L.E., Kovredov, A.I. et al. Unusual splitting of C-H stretching vibration in the spectrum of bis(1-o-carboranyl)methane. Russ Chem Bull 31, 1920–1922 (1982). https://doi.org/10.1007/BF00952406
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DOI: https://doi.org/10.1007/BF00952406