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Recombination of phenothiazine and chloranil ion-radicals in polar media

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Within the framework of the exponential model of an ion-radical pair an equation was obtained, which establishes a relationship between the rate constant of the nonstationary cage recombination of ion-radicals and the fraction of the ions that avoid this process.

  2. 2.

    We determined the numerical values of the mutual diffusion rate constants of the phenothiazine and chloranil ion-radicals and the diffusion separation constants of the ionradical pairs formed by them.

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Literature cited

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    V. K. Turchaninov, K. B. Petrushenko & A. I. Vokin

Authors
  1. V. K. Turchaninov
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  2. K. B. Petrushenko
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  3. A. I. Vokin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2168–2170, September, 1982.

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Turchaninov, V.K., Petrushenko, K.B. & Vokin, A.I. Recombination of phenothiazine and chloranil ion-radicals in polar media. Russ Chem Bull 31, 1918–1920 (1982). https://doi.org/10.1007/BF00952405

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  • DOI: https://doi.org/10.1007/BF00952405

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