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Effect of viscosity on separation of carbon isotopes during photolysis of dibenzyl ketone

  • V. F. Tarasov
  • é. M. Galimov
  • V. I. Mal'tsev
  • A. L. Buchachenko
Brief Communications
  • 18 Downloads

Conclusions

  1. 1.

    The change in the isotopic composition of the dibenzyl ketone and dibenzyl molecules during the photolysis of dibenzyl ketone in solutions of variable viscosity reveals that the enrichment depends on the viscosity in the glycerol-t-BuOH mixtures.

     
  2. 2.

    The main contribution to the isotopic enrichment is made by the primary radical pairs.

     

Keywords

Viscosity Ketone Isotopic Composition Photolysis Carbon Isotope 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    A. L. Buchachenko, é. M. Galimov, V. V. Ershov, G. A. Nikiforov, and A. D. Pershin Dokl. Akad. Nauk SSSR,228, 379 (1976).Google Scholar
  2. 2.
    R. Sagdeev, T. Leshina, and Yu. Molin, Chem. Phys. Lett.,48, 89 (1977).Google Scholar
  3. 3.
    N. Turro, B. Kraeutler, and D. Anderson, J. Am. Chem. Soc.,101, 7435 (1979).Google Scholar
  4. 4.
    V. F. Tarasov, Zh. Fiz. Khim.,54, 2438 (1980).Google Scholar
  5. 5.
    A. L. Buchachenko, V. F. Tarasov, and V. I. Mal'tsev, Zh. Fiz. Khim.,55, 1810 (1981).Google Scholar
  6. 6.
    V. F. Tarasov, D. B. Askerov, and A. L. Buchachenko, Izv. Akad. Nauk SSSR, Ser. Khim1982, 2023.Google Scholar

Copyright information

© Plenum Publishing Corporation 1983

Authors and Affiliations

  • V. F. Tarasov
    • 1
  • é. M. Galimov
    • 1
  • V. I. Mal'tsev
    • 1
  • A. L. Buchachenko
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRMoscow

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