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Transformed steroids 126. Synthesis and stereochemistry of isomeric androsta-D'-pentaranes (15,16-cyclohex-3′-enoandrostanes)

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Condensation of androsta-5,16-diene-17-one with 1,3-dienes at high pressure proceeds nonselectively, and leads to two diastereomeric cycloadducts, while in the presence of anhydrous AlCl3 15Β,16Β-cycloadduct is formed stereospecifically.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    A. V. Kamernitskii, T. N. Galakhova, I. S. Levina, V. A. Pavlov & B. S. él'yanov

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  1. A. V. Kamernitskii
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  2. T. N. Galakhova
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  3. I. S. Levina
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  4. V. A. Pavlov
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  5. B. S. él'yanov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2147–2151, September, 1982.

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Kamernitskii, A.V., Galakhova, T.N., Levina, I.S. et al. Transformed steroids 126. Synthesis and stereochemistry of isomeric androsta-D'-pentaranes (15,16-cyclohex-3′-enoandrostanes). Russ Chem Bull 31, 1896–1900 (1982). https://doi.org/10.1007/BF00952397

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  • DOI: https://doi.org/10.1007/BF00952397

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