Skip to main content
SpringerLink
Log in

Reactions of platinum(O) and palladium(O) complexes with mercury(II) compounds: New methods for the synthesis of organic platinum and palladium derivatives

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

A new group of reactions between Pto and Pdo complexes with organic and heteroorganic HgII compounds was found and studied. The reaction involves the insertion of LnMo into the bond between mercury and the heteroelement. The bimetallic compounds formed may be isolated or undergo immediate demercuration leading to divalent platinum and palladium σ-derivatives, depending on the nature of the substituents and ligands and reaction conditions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. L. Malatesta and S. Cenini, Zerovalent Compounds of Metals, Academic Press, London (1974).

    Google Scholar 

  2. J. P. Coolman and W. P. Roper, Adv. Organomet. Chem.,7, 53 (1968).

    Google Scholar 

  3. R. Ugo, Coord. Chem. Rev.,3, 319 (1968).

    Google Scholar 

  4. J. H. Nelson and H. B. Jonassen, Coord. Chem. Rev.,6, 27 (1971).

    Google Scholar 

  5. O. M. Nefedov and M. N. Manakov, Angew. Chem.,78, 1039 (1966).

    Google Scholar 

  6. K. P. Butin, I. P. Beletskaya, A. N. Kashin, and O. A. Reutov, J. Organomet. Chem.,10, 197 (1967).

    Google Scholar 

  7. K. P. Butin, N. A. Belokoneva, A. A. Zenkin, I. P. Beletskaya, and O. A. Reutov, Dokl. Akad. Nauk SSSR,211, 878 (1973).

    Google Scholar 

  8. V. I. Sokolov, V. V. Bashilov, L. M. Anishchenko, and O. A. Reutov, J. Organomet. Chem.,71, C41 (1974).

    Google Scholar 

  9. V. I. Sokolov, V. V. Bashilov, and O. A. Reutov, J. Organomet. Chem.,97, 299 (1975).

    Google Scholar 

  10. Y. Takahashi, T. Ito. S. Sakai, and Y. Ishii, J. Chem. Soc., Chem. Commun., 1065 (1970).

  11. K. Moseley and P. M. Maitlis, J. Chem. Soc., Chem. Commun., 1604 (1971).

  12. V. I. Sokolov, Section Lecture on the VII ICOMC, Abstracts, SA5, Venice, Italy (1975).

  13. V. I. Sokolov and O. A. Reutov, Coord. Chem. Rev.,27, 89 (1978).

    Google Scholar 

  14. V. V. Bashilov, V. I. Sokolov, and O. A. Reutov, Dokl. Akad. Nauk SSSR,228, 603 (1976).

    Google Scholar 

  15. V. I. Sokolov, E. D. Matveeva, V. V. Bashilov, L. G. Yudin, and A. N. Kost, All-Union Symposium on the Chemistry and Pharmacology of Indole Compounds [in Russian], Shtiintsa, Kishinev (1975), p. 21.

    Google Scholar 

  16. V. V. Bashilov, V. I. Sokolov, G. Z. Suleimanov, and O. A. Reutov, Izv. Akad. Nauk SSSR, Ser. Khim., 2562 (1977).

  17. V. I. Sokolov and V. V. Bashilov, Zh. Org. Khim.,14, 1114 (1978).

    Google Scholar 

  18. G. Z. Suleimanov, V. V. Bashilov, V. I. Sokolov, and O. A. Reutov, Izv. Akad, Nauk SSSR, Ser. Khim., 1670 (1978).

  19. V. I. Sokolov, G. Z. Suleimanov, V. V. Bashilov, T. Kh. Kurbanov, I. A. Amiraslanov, and O. A. Reutov, Izv. Akad. Nauk SSSR, Ser. Khim., 1894 (1977).

  20. O. A. Reutov, V. I. Sokolov, G. Z. Suleimanov, V. V. Bashilov, and I. A. Amiraslanov, Izv. Akad. Nauk SSSR, Ser. Khim., 2147 (1977).

  21. V. I. Sokolov, A. A. Musaev, V. V. Bashilov, and O. A. Reutov, Izv. Akad. Nauk SSSR, Ser. Khim., 2409 (1981).

  22. G. Oehme, K. C. Rober, and H. Pracejus, J. Organometal. Chem.,105, 127 (1976).

    Google Scholar 

  23. L. I. Zakharkin and I. V. Pisareva, Izv. Akad. Nauk SSSR, Ser. Khim., 252 (1978).

  24. L. Y. Chia and W. R. McWhinney, J. Organomet. Chem.,188, 121 (1980).

    Google Scholar 

  25. E. R. Milaeva, A. Z. Rubezhov, A. I. Prokof'ev (Prokofiev), A. G. Milaev, and O. Yu. Okhlobystin, J. Organomet. Chem.,188, C43 (1980).

    Google Scholar 

  26. J. Chatt and B. L. Shaw, J. Chem. Soc.,705, 4020 (1959).

    Google Scholar 

  27. J. Müller and P. Göser, Angew. Chem.,79, 380 (1967).

    Google Scholar 

  28. J. A. Labinger, A. V. Kramer, and J. A. Osborne, J. Am. Chem. Soc.,95, 7980 (1973).

    Google Scholar 

  29. L. L. Troitskaya, A. I. Grandberg, V. I. Sokolov, and O. A. Reutov, Dokl. Akad. Nauk SSSR,228, 367 (1976).

    Google Scholar 

  30. J. Chatt and B. L. Shaw, J. Chem. Soc., 5075 (1962).

  31. R. G. Pearson, W. Louw, and J. Rajaram, Inorg. Chim. Acta,9, 251 (1974).

    Google Scholar 

  32. O. A. Reutov, V. I. Sokolov, G. Z. Suleimanov, and V. V. Bashilov, J. Organomet. Chem.,160, 7 (1978).

    Google Scholar 

  33. A. Z. Rubezhoy, A. S. Ivanov, and S. P. Gubin, Izv. Akad. Nauk SSSR, Ser. Khim., 2348 (1976).

  34. A. N. Nesmeyanov and A. Z. Rubezhov, J. Organomet. Chem.,164, 259 (1979).

    Google Scholar 

  35. V. I. Sokolov, V. V. Bashilov, and O. A. Reutov, J. Organomet. Chem.,111, C13 (1976).

    Google Scholar 

  36. W. J. Cherwinski, B. F. G. Johnson, and J. Lewis, J. Chem. Soc., Dalton Trans., 1405 (1974).

  37. V. I. Sokolov, L. L. Troitskaya, and O. A. Reutov, J. Organomet. Chem.,93, C11 (1975).

    Google Scholar 

  38. B. DiBlazio, A. Panunzi, C. Pedone, and A. Vitagliano, Gazz. Chim. Ital.,106, 709 (1976).

    Google Scholar 

  39. I. M. Al-Najjar, M. Green, S. J. S. Kerrison, and P. J. Sadler, J. Chem. Soc., Chem. Commun., 311 (1979).

  40. I. M. Al-Najjar, M. Green, J. K. K. Sarhan, I. M. Ismail, and P. J. Sadler, Inorg. Chim. Acta,44, L187 (1980).

    Google Scholar 

  41. V. I. Sokolov, V. V. Bashilov, A. A. Musaev, and O. A. Reutov, J. Organomet. Chem.,225, 57 (182).

  42. V. I. Sokolov, V. V. Bashilov, and O. A. Reutov, Abstracts of the Twelfth Mendeleev Congress [in Russian], Vol. 1, Nauka, Moscow (1981), p. 424.

    Google Scholar 

  43. V. V. Bashilov, A. A. Musaev, and V. I. Sokolov, The Tenth ICOMC, Abstracts, 2E88, Toronto, Canada (1981), p. 293.

  44. O. A. Reutov, V. V. Bashilov, and V. I. Sokolov, Izv. Akad. Nauk SSSR, Ser. Khim., 1169 (1981).

  45. L. L. Troitskaya, V. I. Sokolov, and O. A. Reutov, Dokl. Akad. Nauk SSSR,236, 371 (1977).

    Google Scholar 

  46. A. J. Layton, R. S. Nyholm, G. A. Pneumaticakis, and M. L. Tobe, Chem. Ind., 465 (1967).

  47. L. G. Kuz'mina, Yu. T. Struchkov, V. V. Bashilov, V. I. Sokolov, and O. A. Reutov, Izv. Akad. Nauk SSSR, Ser. Khim., 621 (1978).

  48. V. I. Sokolov, V. V. Bashilov, L. L. Troitskaya, M. N. Bochkarev, G. Z. Suleimanov, and O. A. Reutov, Abstracts of the Second All-Union Conference on the Chemistry of Carbenes and Their Analogs [in Russian], Moscow (1977), p. 52.

  49. O. A. Reutov, G. Z. Suleimanov, A. I. Amiraslanov, V. V. Bashilov, and V. I. Sokolov, Zh. Org. Khim.,14, 1802 (1978).

    Google Scholar 

  50. V. V. Bashilov, V. I. Sokolov, G. Z. Suleimanov, and O. A. Reutov, Izv. Akad. Nauk SSSR, Ser. Khim., 2563 (1977).

  51. V. I. Sokolov, G. Z. Suleimanov, V. V. Bashilov, A. A. Musaev, and O. A. Reutov, J. Organomet. Chem.,202, C61 (1980).

    Google Scholar 

  52. V. I. Sokolov, A. A. Musaev, and G. Z. Suleimanov, Izv. Akad. Nauk SSSR, Ser. Khim., 1177 (1980).

  53. é. V. Uglova, V. D. Makhaev, and O. A. Reutov, Dokl. Akad. Nauk SSSR,188, 838 (1969).

    Google Scholar 

  54. V. I. Sokolov, V. V. Bashilov, O. A. Reutov, M. N. Bochkarev, L. P. Maiorova (Mayorova), and G. A. Razuvaev, J. Organomet. Chem.,112, C47 (1976).

    Google Scholar 

  55. M. N. Bochkarev, G. A. Razuvaev, L. P. Maiorova (Mayorova), V. I. Sokolov, N. P. Makarenko, V. V. Bashilov, and O. A. Reutov, J. Organomet. Chem.,131, 399 (1977).

    Google Scholar 

  56. T. N. Teplova, L. G. Kuz'mina, Yu. T. Struchkov, V. I. Sokolov, V. V. Bashilov, M. N. Bochkarev, L. P. Maiorova, and P. V. Petrovskii, Koord. Khim.,6, 134 (1980).

    Google Scholar 

  57. F. Basolo and R. G. Pearson, Mechanisms of Inorganic Reactions, Wiley (1967).

  58. V. I. Sokolov and G. Z. Suleimanov, Inorg. Chim. Acta,25, L149 (1977).

    Google Scholar 

  59. M. N. Bochkarev, L. P. Maiorova, and G. A. Razuvaev, Zh. Obshch. Khim.,50, 903 (1980).

    Google Scholar 

  60. V. I. Sokolov, L. L. Troitskaya, T. A. Sorokina, and O. A. Reutov, J. Organomet. Chem.,36, 389 (1972).

    Google Scholar 

  61. E. G. Mednikov, N. K. Eremenko, A. I. Ponomarchuk, and N. L. Zhuravleva, Abstracts of the Twelfth Chugaev Conference [in Russian], Moscow (1978).

  62. E. G. Mednikov, N. K. Eremenko, V. A. Mikhailov, S. P. Gubin, Yu. A. Slovokhotov, and Yu. T. Struchkov, J. Chem. Soc., Chem. Commun., 989 (1981).

  63. K. Kitaura, S. Obara, and K. Morokuma, J. Am. Chem. Soc.,103, 2891 (1981).

    Google Scholar 

  64. K. S. Y. Lau, R. W. Fries, and J. K. Stille, J. Am. Chem. Soc.,96, 4983 (1974).

    Google Scholar 

  65. V. I. Sokolov, O. A. Reutov, G. Z. Suleimanov, V. I. Rozenberg (Rosenberg), P. V. Petrovskii, A. I. Lutsenko, and E. I. Fedin, J. Organomet. Chem.201, 29 (1980).

    Google Scholar 

  66. O. A. Reutov, G. Z. Suleimanov, V. I. Rozenberg, A. I. Lutsenko, é. I. Fedin, and V. I. Sokolov, Izv. Akad. Nauk SSSR, Ser. Khim., 470 (1979).

  67. J. Chatt, R. S. Coffey, A. Gough, and D. T. Tompson, J. Chem. Soc., A, 190 (1968).

    Google Scholar 

  68. E. G. Mednikov and N. K. Eremenko, Izv. Akad. Nauk SSSR, Ser. Khim., 2400 (1981).

  69. I. Omae, Chem. Rev.,79, 287 (1979).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    V. V. Bashilov, V. I. Sokolov & O. A. Reutov

Authors
  1. V. V. Bashilov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. I. Sokolov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. O. A. Reutov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Article published by a decision of the editorial board of this journal, dated December 3. 1981.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2069–2089, September, 1982.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bashilov, V.V., Sokolov, V.I. & Reutov, O.A. Reactions of platinum(O) and palladium(O) complexes with mercury(II) compounds: New methods for the synthesis of organic platinum and palladium derivatives. Russ Chem Bull 31, 1825–1842 (1982). https://doi.org/10.1007/BF00952385

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00952385

Keywords

Search

Navigation