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Polarizability anisotropy of some phenyl- and benzylsilanes

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The major semiaxes of the polarizability ellipsoid of the\(C_{sp^2 } ---Si\) bond in trimethylphenylsilane have been calculated.

  2. 2.

    Diphenyldimethylsilane and diphenyldichlorosilane have a conformation corresponding to C2 symmetry, the angle of rotation of the phenyl group relative to the coplanar form being ∼ 40‡.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch of the Academy of Sciences of the USSR, USSR

    A. P. Timosheva, A. N. Vereshchagin, V. F. Traven', O. G. Rodin & B. I. Stepanov

  2. D. I. Mendeleev Institute of Chemical Technology, Moscow

    A. P. Timosheva, A. N. Vereshchagin, V. F. Traven', O. G. Rodin & B. I. Stepanov

Authors
  1. A. P. Timosheva
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  2. A. N. Vereshchagin
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  3. V. F. Traven'
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  4. O. G. Rodin
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  5. B. I. Stepanov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2065–2068, September, 1982.

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Timosheva, A.P., Vereshchagin, A.N., Traven', V.F. et al. Polarizability anisotropy of some phenyl- and benzylsilanes. Russ Chem Bull 31, 1821–1823 (1982). https://doi.org/10.1007/BF00952384

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  • DOI: https://doi.org/10.1007/BF00952384

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