Skip to main content
SpringerLink
Log in

Kinetics of the oligomerization of hexafluoropropylene oxide, initiated by cesium fluoride in tetraglyme

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The initial rate of the oligomerization of the oxide of hexafluoropropylene is first-order in the oxide and something close to first-order (0.8) in the CsF.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. USA Patent, 3125599, 1964.

  2. USA Patent, 3222826, 1967.

  3. USA Patent, 3412148, 1968.

  4. USA Patent, 3449389, 1969.

  5. H. S. Eleuterio, J. Macromol. Sci. Chem.,A-6, 1027 (1972).

    Google Scholar 

  6. J. T. Hill, J. Macromol. Sci. Chem.,A-8, 499 (1974).

    Google Scholar 

  7. I. A. Knunyants, A. V. Fokin, and Yu. A. Cheburkov, Zh. Vses. Khim. O-va im. D. I. Mendeleeva,13, 311 (1968).

    Google Scholar 

  8. T. G. Shchibrya, S. P. Krukovskii, and V. A. Ponomarenko, Third All-Union Conference. Heterogeneous Catalysis in the Chemistry of Heterocyclic Compounds, Riga (1981), p. 71.

  9. V. A. Ponomarenko, S. P. Krukovskii, and A. Yu. Alybina, Fluorine-Containing Heterochain Polymers [in Russian], Nauka, Moscow (1973), p. 56.

    Google Scholar 

  10. T. G. Shchibrya, A. V. Ignatenko, S. P. Krukovskii, and V. A. Ponomarenko, Izv. Akad. Nauk SSSR, Ser. Khim., 700 (1980).

  11. J. T. Hill and J. P. Erdman, Polym. Prepr.,18, 1 (1977).

    Google Scholar 

  12. T. G. Shchibrya, A. V. Ignatenko, S. P. Krukovskii, and V. A. Ponomarenko, Vysokomol. Soed.,A-13, 1805 (1976).

    Google Scholar 

  13. Organic Course. Laboratory Manual in Organic Chemistry [Russian translation], Mir, Moscow (1979), Vol. 2, p. 295.

  14. F. Ya. Kul'b (editor), Handbook for Laboratory Work in General and Inorganic Chemistry [in Russian], Goskhimizdat, Leningrad (1976).

    Google Scholar 

  15. F. Daniels et al., Experimental Physical Chemistry, McGraw-Hill (1962).

  16. S. L. Kiperman, Introduction to the Kinetics of Heterogeneous Catalytic Reactions [in Russian], Nauka, Moscow (1964), p. 514.

    Google Scholar 

  17. V. A. Roiter (editor), Problems of Theory and Practice in the Field of Catalysis [in Russian], Naukova Dumka, Kiev (1973), p. 189.

    Google Scholar 

  18. V. M. Ramm, Adsorption Processes in Industrial Chemistry [in Russian], Goskhimizdat, Moscow-Leningrad (1951), p. 59.

    Google Scholar 

  19. M. Swarcz, Anionic Polymerization [Russian translation], Mir, Moscow (1971).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    T. G. Shchibrya, S. P. Krukovskii & V. A. Ponomarenko

Authors
  1. T. G. Shchibrya
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. P. Krukovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. A. Ponomarenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1999–2004, September, 1982.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shchibrya, T.G., Krukovskii, S.P. & Ponomarenko, V.A. Kinetics of the oligomerization of hexafluoropropylene oxide, initiated by cesium fluoride in tetraglyme. Russ Chem Bull 31, 1765–1769 (1982). https://doi.org/10.1007/BF00952372

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00952372

Keywords

Search

Navigation