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Study of cyclo-C6H11 \(C_{sp^2 } ---Si\) radical reactions through critical effects in nonchain radical processes

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A new method for studying critical effects in nonchain radical processes is proposed; this is based on an ESR study of the relation existing between the initial rate of radical formation and the reactant concentration.

  2. 2.

    The critical concentration of phenol, the rate constant for isomerization of the cyclo-C6H11 \(C_{sp^2 } ---Si\) radical, and the reactions of this radical with cyclohexane, the phenol, and CPC have been studied in the dicyclohexylperoxydicarbonate (CPC)-2, 4, 6-tri-tert-butylphenol-benzene system.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    V. A. Roginskii & V. A. Belyakov

Authors
  1. V. A. Roginskii
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  2. V. A. Belyakov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1980–1987, September, 1982.

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Roginskii, V.A., Belyakov, V.A. Study of cyclo-C6H11 \(C_{sp^2 } ---Si\) radical reactions through critical effects in nonchain radical processes. Russ Chem Bull 31, 1749–1754 (1982). https://doi.org/10.1007/BF00952369

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  • DOI: https://doi.org/10.1007/BF00952369

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