Structure of phosphoryl compounds containing halomethyl groups

  • O. A. Raevskii
  • N. G. Mumzhieva
Physical Chemistry
  • 14 Downloads

Conclusions

  1. 1.

    For bromomethyldimethyl- and iodomethyldimethylphosphine oxides a relationship between SSCC of methylene signals and conformation composition has been shown and the parameters for separate conformers have been estimated on the basis of PMR spectra and available data on IR spectra.

     
  2. 2.

    The three-dimensional structure of more complex molecules has been identified. A pronounced tendency towards decrease of the weight of conformers with trans arrangement of several carbon-halogen bonds in the series Cl, Br, and I derivatives was observed.

     

Keywords

Oxide Methylene Phosphoryl Complex Molecule Methylene Signal 

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Copyright information

© Plenum Publishing Corporation 1982

Authors and Affiliations

  • O. A. Raevskii
    • 1
  • N. G. Mumzhieva
    • 1
  1. 1.Institute of Physiologically Active SubstancesAcademy of Sciences of the USSRChernogolovka

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