Advertisement

Fluoroolefin oxides. 1. A new method of synthesis of perfluorinated epoxyalkanes

  • I. P. Kolenko
  • T. I. Filyakova
  • A. Ya. Zapevalov
  • É. P. Lur'e
Organic Chemistry

Conclusions

  1. 1.

    A new, convenient method has been developed for the epoxidation of terminal and internal perfluoroolefins by alkali and alkaline-earth hypohalites in alkaline solution in the presence of aprotic solvents.

     
  2. 2.

    In the presence of nucleophilic and electrophilic catalysts the oxides of internal perfluoroolefins are isomerized to ketones.

     

Keywords

Oxide Ketone Epoxidation Alkaline Solution Convenient Method 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    P. Tarrant and E. Stamp, Zh. Vses. Khim. O-va.,15, 34 (1970).Google Scholar
  2. 2.
    K. W. Jolley, L. H. Lutclibbe, and K. L. Williamson, Spectrochim. Acta,30A, 1455 (1974).Google Scholar
  3. 3.
    Handbook on Preparative Inorganic Chemistry [Russian translation], IL (1956), p. 165.Google Scholar
  4. 4.
    A. Ya. Zapevalov, I. P. Kolenko, V. S. Plashkin, and P. G. Neifel'd, Zh. Org. Khim.,14, 259 (1978).Google Scholar

Copyright information

© Plenum Publishing Corporation 1980

Authors and Affiliations

  • I. P. Kolenko
    • 1
  • T. I. Filyakova
    • 1
  • A. Ya. Zapevalov
    • 1
  • É. P. Lur'e
    • 1
  1. 1.Institute of Chemistry, Urals Scientific CenterAcademy of Sciences of the USSRSverdlovsk

Personalised recommendations