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Telomerization of ethylene with dimethylacetal

  • O. G. Safiev
  • U. B. Imashev
  • A. B. Terent'ev
Organic Chemistry
  • 19 Downloads

Conclusions

  1. 1.

    Telomerization of ethylene with acetaldehyde dimethylacetal gives three series of products: acetals CH3CH(OCH3)OCH2(CH2CH2)nH (n=1-3), acetates CH2CO2CH2(CH2CH2)nH (n= 1 and 3), and ketones CH2CO(CH2CH2)nH (n=1-3).

     
  2. 2.

    To account for the formation of propyl and heptyl acetates a scheme has been proposed which includes the rearrangement of the growing radicals with 1,5- and 1,9- migration of hydrogen, respectively.

     

Keywords

Hydrogen Acetate Ethylene Migration Ketone 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    V. P. Nayanov, V. V. Zorin, S. S. Zlot-skii, A. B. Terent'ev, and D. L. Rakhmankulov, Zh. Prikl. Khim.,48, 2773 (1975).Google Scholar
  2. 2.
    V. P. Nayanov, D. L. Rakhmankulov, S. S. Zlot-skii, and A. B. Terent'ev, Izv. Akad. Nauk SSSR, Ser. Khim., 594 (1975).Google Scholar
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    O. G. Safiev, U. B. Imashev, S. S. Zlot-skii, D. L. Rakhmankulov, and A. B. Terent'ev, Izv. Akad. Nauk SSSR, Ser. Khim., 2786 (1978).Google Scholar
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    L. A. Yanovskaya, S. S. Yufit, and V. F. Kucherov, The Chemistry of Acetals [in Russian], Nauka (1975), p. 252.Google Scholar
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    J. L. Nedelec and D. Lefort, Tetrahedron,31, 411 (1975).Google Scholar
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    N. S. Ikonnikov, A. B. Terent'ev, M. A. Churilova, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 479 (1972).Google Scholar
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    T. Fujimoto and J. Hirao, Bull. Chem. Soc. Jpn.,47, 1930 (1974).Google Scholar

Copyright information

© Plenum Publishing Corporation 1980

Authors and Affiliations

  • O. G. Safiev
    • 1
  • U. B. Imashev
    • 1
  • A. B. Terent'ev
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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